Fluorescence optosensor using an artificial neural network for screening of polycyclic aromatic hydrocarbons

This paper presents an optosensor for screening of four polycyclic aromatic hydrocarbons: anthracene (ANT), benzo[a]pyrene (BaP), fluoranthene (FLT), and benzo[b]fluoranthene (Bbf) using a photomultiplier device with an artificial neural network as transducer. The optosensor is based on the on-line immobilization on a non-ionic resin (Amberlite XAD-4) solid support in a continuous flow. The determination was performed in 15 mM H2PO4−/HPO42− buffer solution at pH 7 and 25% of 1,4-dioxane. Feed forward neural networks (multiplayer perceptron) have been trained to quantify the considered Polycyclic aromatic hydrocarbons (PAHs) in mixtures under optimal conditions. The optosensor proposed was also applied satisfactorily to the determination of the considered PAHs in water samples in presence of the other 12 EPA–PAHs. © 2004 Elsevier B.V. All rights reserved.